Methyl bromide is an organobromine compound with the chemical formula CH₃Br. This compound is produced in nature as well as in the lab. It is estimated that approximately 1 to 2 billion kilograms of methyl bromide is naturally produced by marine organisms annually. In the lab, methyl bromide is produced by reacting methanol with hydrogen bromide. Methyl bromide is a colorless, tasteless, odorless, and nonflammable gas that is registered with the EPA as an herbicide, fungicide, nematicide and insecticide. The chemical chloropicrin is often added to methyl bromide as an odorant, in small amounts, and as a fungicide in ratios containing more than 50% chloropicrin.
There are three main factors that influence the efficacy of methyl bromide; soil moisture, soil temperature, and soil tilth.
· Soil Moisture: Soils with too much, or too little moisture can reduce the efficacy of methyl bromide fumigation. When soils are too wet, the fumigant can become diluted, reducing its sterilizing potential. However, soils that are too dry also pose a problem. Soils that don’t have enough moisture tend to allow the methyl bromide to move through the soil profile too quickly. The soil should be kept wet for at least one week prior to the fumigation to allow for the germination of weed seeds. Just before the fumigation is to take place, the soil should be dried to the equivalent of slight dampness.
· Soil Temperature: The higher the soil temperature, the easier it is for methyl bromide to vaporize. At soil temperatures above 40°F, methyl bromide will readily vaporize and diffuse through the air and soil.
· Soil Tilth: Methyl bromide works the best when applied to loose, tilled soils that are free of weeds and other organic debris. Soils should also be cultivated prior to fumigation. The depth at which the soil is cultivated will be approximately equivalent to the depth at which the methyl bromide penetrates. For the best results, a penetration depth of 8 to 10 inches is recommended. Areas that are under vegetation should be scalped and aerified before the fumigation process.
There are two methods for methyl bromide application; the hot gas method and the tractor applied method. Both methods require a certified applicator and commonly consist of application rates from 100 to 400 lbs of active ingredient per acre. The plastic coverings can be removed from the treated areas in as fast as 3 hours per fairway or 5 hours for 18 greens. The hot gas method was recently used at the ISU Horticulture Research Station to fumigate an area that had previously been established to roundup ready bentgrass.
· Hot Gas Method: The hot gas method is used whenever the mechanical application method is not an option due to space, access, terrene or no till application. Usually treats 120,000 ft² per day.
Step 1: T-tape drip tubing is placed at 6 ft. intervals assuring even distribution of the gas over the entire area to be treated.
· Hot Gas Method: The hot gas method is used whenever the mechanical application method is not an option due to space, access, terrene or no till application. Usually treats 120,000 ft² per day.
Step 1: T-tape drip tubing is placed at 6 ft. intervals assuring even distribution of the gas over the entire area to be treated.
Step 2: Hand lay polyethylene tarps over the treated area securing seems with quick dry fumigant adhesive and covering the edges with dirt or a layer of pre-cut sod.
Step 3: Methyl bromide is forced through a heat exchanger and into the drip tubing. Scales are used to determine the precise amount of fumigant used.
Step 4: Polyethylene tarps can be removed after 48 hrs. or when the methyl bromide concentrations are below 5ppm.
· Tractor Applied Method: The tractor applied method is used any time the undulation and area allow for its implication. Each machine is capable of treating approximately 1 large par 5, 2 par 3’s, 250,000 ft² of sports field, or 20 acres of sod farm per day. Each machine injects methyl bromide 8 to 10 inches deep through solid knives. Once the methyl bromide is injected, the machine covers the soil with high barrier polyethylene tarps.
· Tractor Applied Method: The tractor applied method is used any time the undulation and area allow for its implication. Each machine is capable of treating approximately 1 large par 5, 2 par 3’s, 250,000 ft² of sports field, or 20 acres of sod farm per day. Each machine injects methyl bromide 8 to 10 inches deep through solid knives. Once the methyl bromide is injected, the machine covers the soil with high barrier polyethylene tarps.
Methyl bromide has been a very effective chemical for sterilizing soil systems. However, methyl bromide is currently being phased out due to its potential harm to the ozone layer and human health. Soil sterilization, never the less, will remain a common practice as it promises to prolong the development of problematic weeds, soil borne diseases, nematodes, and soil borne insect problems in newly established turf. For more information on mehtyl bromide fumigation visit http://www.hendrixanddail.com/index.asp
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